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To explain the last part of this Skill, essentially if you have 2 Skills that would meet their activation requirements at the same time and happen to be a Skill that can be used during the opponents turn, the order in which you resolve them is turn player, followed by the other player

You can only use this effect of "Performapal Barracuda" once per turn

For play

Once per turn, when your opponent activates a Spell Card or effect (Quick Effect): You can place this card in your Pendulum Zone, and if you do, negate that effect, then, if you placed this Ritual Summoned card in the Pendulum Zone, you can Special Summon 1 "Odd-Eyes" monster from your Extra Deck.